Marcus rate theory applied to enzymatic proton transfer
نویسندگان
چکیده
منابع مشابه
Optimal rates for electron transfer in Marcus theory.
We examine electron transfer between two quantum states in the presence of a dissipative environment represented as a set of independent harmonic oscillators. For this simple model, the Marcus transfer rates can be derived from the equations of motion for electronic operators and we show that these rates are associated to an explicit expression for the environment correlation time. We demonstra...
متن کاملWealth inhomogeneity applied to crash rate theory
A crash rate theory based on corporate economic utility maximization is applied to individual behavior in U.S. and German motorway death rates, by using wealth inhomogeneity data in ten-percentile bins to account for variations of utility maximization in the population. Germany and the U.S. have similar median wealth figures, a well-known indicator of accident risk, but different motorway death...
متن کاملEnzymatic Catalysis of Proton Transfer and Decarboxylation Reactions.
Deprotonation of carbon and decarboxylation at enzyme active sites proceed through the same carbanion intermediates as for the uncatalyzed reactions in water. The mechanism for the enzymatic reactions can be studied at the same level of detail as for nonenzymatic reactions, using the mechanistic tools developed by physical organic chemists. Triosephosphate isomerase (TIM) catalyzed interconvers...
متن کاملRadiative transfer theory applied to ocean bottom modeling.
Research on the propagation of acoustic waves in the ocean bottom sediment is of interest for active sonar applications such as target detection and remote sensing. The interaction of acoustic energy with the sea floor sublayers is usually modeled with techniques based on the full solution of the wave equation, which sometimes leads to mathematically intractable problems. An alternative way to ...
متن کاملExplain the optimal pattern in the contracts of public private Participation construction, exploitation and transfer (BOT) Applied to Contracts Theory
In recent decade in developing countries, lack of government budget or lack of access to modern technology, persuade governments to attract private sector participation in the economy. One of the most common methods is Public-Private Partnership agreements. The real implementation of this type of partnership needs to set contracts that satisfies preferences of both parties. This research aims t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Biochimica et Biophysica Acta (BBA) - Bioenergetics
سال: 2000
ISSN: 0005-2728
DOI: 10.1016/s0005-2728(00)00061-x